The Synthesis of a Novel Tripodal Nitrogen Ligand MIZ3tren and its Cobalt Acetate Coordination Complex

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The Synthesis of a Novel Tripodal Nitrogen Ligand MIZ3tren and its Cobalt Acetate Coordination Complex

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Title: The Synthesis of a Novel Tripodal Nitrogen Ligand MIZ3tren and its Cobalt Acetate Coordination Complex
Author: Witt, Jonathan
Advisor: Scarrow, Robert C.
Department: Haverford College. Department of Chemistry
Type: Thesis (B.S.)
Issue Date: 2011
Abstract: The synthesis of the novel tripodal nitrogen ligand N1,N2,N3-tris(2- (imidazolidin-2-ylideneamino)ethyl)amine (MIZ3tren) is reported. A synthetic technique based on literature precedent was used. However, the exact conditions reported in the literature did not work for this particular synthesis. An ordered series of optimization reactions were conducted that eventually led to the appropriate reaction conditions. MIZ3tren was obtained in pure form but unknown yield. The purified ligand was reacted with cobalt acetate tetrahydrate to give the coordination complex [Co2+MIZ3tren(OAc-)]OAc-.
Subject: Cobalt Acetate Tetrahydrate
Subject: Ligands -- Synthesis
Subject: MIZ3tren -- Synthesis
Terms of Use: http://creativecommons.org/licenses/by-nc/3.0/us/
Permanent URL: http://hdl.handle.net/10066/8064

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Citation

Witt, Jonathan. "The Synthesis of a Novel Tripodal Nitrogen Ligand MIZ3tren and its Cobalt Acetate Coordination Complex". 2011. Available electronically from http://hdl.handle.net/10066/8064.

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